Ionization Energies in kJ/mol

  1 2 3 4 5 6 7 8
H 1312              
He 2372 5250            
Li 520 7297 11810          
Be 899 1757 14845 21000        
B 800 2426 3659 25020 32820      
C 1086 2352 4619 6221 37820 47260    
N 1402 2855 4576 7473 9442 53250 64340  
O 1314 3388 5296 7467 10987 13320 71320 84070
F 1680 3375 6045 8408 11020 15160 17860 92010
Ne 2080 3963 6130 9361 12180 15240    
Na 496 4563 6913 9541 13350 16600 20113 25666
Mg 737 1450 7731 10545 13627 17995 21700 25662

The teal colored cells represent ionization energies where the valence shell is now (n-1).

Why do you think there is such a large jump in the ionization energies when the n-1 shell is now valence?